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Sulfanylamide-containing coordination compounds of 3d-elements with 2,4-pentanedione bis-thiosemicarbazone and bis-4-phenylthiosemicarbazone

✍ Scribed by A. P. Gulya; S. N. Spynu; V. I. Tsapkov; D. Poirer


Book ID
111459664
Publisher
Springer
Year
2008
Tongue
English
Weight
176 KB
Volume
78
Category
Article
ISSN
1070-3632

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✍ Lucia Balazs; HansΒ J. Breunig; Enno Lork; Cristian Silvestru πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 148 KB

## Abstract The cyclobismuthanes R~__n__~Bi~__n__~, [R = 2‐(Me~2~NCH~2~)C~6~H~4~; __n__ = 3 (1a), 4 (1b)] have been synthesised by reduction of RBiCl~2~ with Na in liquid NH~3~ or by reaction of R~2~BiCl with LiAlH~4~ in Et~2~O. The reaction of 1a/b with W(CO)~5~Β·THF afforded the bismuthinidene com