𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Low-Valent Organobismuth Compounds with Intramolecular Coordination: cyclo-R3Bi3, cyclo-R4Bi4, RBi[W(CO)5]2, and R4Bi2 [R = 2-(Me2NCH2)C6H4]

✍ Scribed by Lucia Balazs; Hans J. Breunig; Enno Lork; Cristian Silvestru

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
148 KB
Volume
2003
Category
Article
ISSN
1434-1948

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The cyclobismuthanes R~n~Bi~n~, [R = 2‐(Me~2~NCH~2~)C~6~H~4~; n = 3 (1a), 4 (1b)] have been synthesised by reduction of RBiCl~2~ with Na in liquid NH~3~ or by reaction of R~2~BiCl with LiAlH~4~ in Et~2~O. The reaction of 1a/b with W(CO)~5~·THF afforded the bismuthinidene complex RBi[W(CO)~5~]~2~ (2). R~2~BiCl reacts with Mg in THF to give the dibismuthane R~4~Bi~2~ (3). Single‐crystal X‐ray structure analyses of 1b, 2, and 3 reveal intramolecular coordination of the pendant CH~2~NMe~2~ groups to the bismuth atom. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

📜 SIMILAR VOLUMES

P−H-Functionalized Phosphanyl Alcohols:
P−H-Functionalized Phosphanyl Alcohols: RHPCH2CHMeOH and 2-PHR-1-OH-cyclo-C6H10 (R = Ph, 2,4,6-Me3C6H2, 2,4,6-iPr3C6H2) and Molecular Structures of (CR,CR,PR/CS,CS,PS)-2-PH(2,4,6-iPr3C6H2)-1-OH-cyclo-C6H10 and its Dilithio Salt [Li2(THF)0.5{(CR,CR/CS,CS)-2-P(2,4,6-iPr3C6H2)-1-O-cyclo-C6H10}]4
✍ Thomas Koch; Steffen Blaurock; Fernando Somoza, Jr.; Evamarie Hey-Hawkins 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 390 KB 👁 1 views
Syntheses and Structures of Bis(aryloxo)
Syntheses and Structures of Bis(aryloxo)fluoroytterbium(III) Complexes, [Yb(OAr)2F(THF)]2 (OAr = OC6H2-2,6-tBu2-4-R; R = H, Me, tBu), and Bis(cyclopentadienyl)fluoroytterbium(III) Complexes, [YbCp2F]3, [Yb(MeCp)2F]4, [YbCp2F(OPPh3)]2, and [Yb(MeCp)2F(THF)]2
✍ Glen B. Deacon; Gerd Meyer; Dirk Stellfeldt 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 546 KB

Reaction of [Yb(OAr) 2 (THF) 3 ] (OAr = OC 6 H 2 -2,6-tBu 2 -4-R; R = H, Me, tBu) with perfluorodecalin in THF at room temperature results in C-F activation and formation of the first heteroleptic aryloxofluorolanthanoid complexes, [Yb-(OAr) 2 F(THF)] 2 . Oxidation of bis(cyclopentadienyl)ytterbium(