A mathematical model for the isothermal reaction between a fluid and a porous solid, in pelletgrain form, is studied. First, an analytical derivation of the time for total conversion is presented. Then the differential equations, given as a coupled pair of time-dependent and time-independent equatio
Successive gas-solid reactions in a porous pellet: Application to the reaction of metal sulfides in the presence of lime
β Scribed by H.Y. Sohn; K. Rajamani
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 902 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0009-2509
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β¦ Synopsis
Ah&act
-A general model 1s presented for the descnpbon of successive gas-solid reactions occumng m a porous pellet Such reaction systems have begun attracting much attention mamly m the treatment of metal sulfides m the presence of luue The use of lime has been proposed as an alternative to the conventional processes which produce sulfur-contauung pollutants The model has been formulated m qmte generai terms such that specific details can easily be incorporated when It 1s apphed to an actual system The model enables us to predrct the rate of conversion and the extent of fixatrop of the mtermediate gas (sulfur-contammg gas) m the sohd &me) Other potenti apphcations of the model are dlscussed m the text 1 DITRODUCTION
π SIMILAR VOLUMES
The partially sintered spheres model is further developed to account for the influence of inert material present in the solid reactant. This model is applicable, for example, to the sulphation of CaO with a variable amount of inert material. An example is the reaction between calcined dolomite, CaO'
The mass transport equation applymg to a second order gas sohd reactlon takmg place m an Isothermal spherical particle IS solved by the orthogonal collocation method, usmg 3, 5 and 8 pomt collocation The results are compared with those obtamed m earher studies usmg different assumptions and calculat
Solventless reactions are currently a subject of extensive interest in both inorganic and organic chemistry. [1] In particular, organic synthesis may benefit from avoiding the use of organic solvents, yet this is valid only if a whole process, including work-up operations, is free from organic solve