Substrate effects on the magnetic ground state of 3d transition metal chains
β Scribed by M.C. Urdaniz; M.A. Barral; A.M. Llois
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 263 KB
- Volume
- 404
- Category
- Article
- ISSN
- 0921-4526
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π SIMILAR VOLUMES
Magnetic and optical properties of transition-metal complexes are governed by the ground state and the low-energy excitation spectrum of the d-shell of the central transition metal ion. These spectra are successfully fit to the crystal field theory. We present here an account of the effective Hamilt
## Abstract By means of the ΞSCF and transition operator (TO) methods based on a recently developed INDO extension to the first transition metal series, the first ionization potentials of benzeneβchromium tricarbonyl (**I**), cyclopentadienyl manganese tricarbonyl (**II**), the ironβtricarbonyl com