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Ground-state multiplicities and d—d excitations of transition-metal complexes by effective Hamiltonian method

✍ Scribed by A. V. Soudackov; A. L. Tchougréeff; I. A. Misurkin

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
979 KB
Volume
58
Category
Article
ISSN
0020-7608

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✦ Synopsis

Magnetic and optical properties of transition-metal complexes are governed by the ground state and the low-energy excitation spectrum of the d-shell of the central transition metal ion. These spectra are successfully fit to the crystal field theory. We present here an account of the effective Hamiltonian method recently developed to calculate the ground state and the excitations of the d-shells of transition-metal complexes and report the results of its application to some complexes of particular interest.

📜 SIMILAR VOLUMES

Crystal-field splittings and optical spe
Crystal-field splittings and optical spectra of transition-metal mixed-ligand complexes by effective Hamiltonian method
✍ A. V. Soudackov; A. L. Tchougreeff; I. A. Misurkin 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 818 KB

Many of the important properties of transition-metal complexes depend on the low-energy excitation spectrum formed by d-electrons of the central transition-metal atom. The spectra of this type are usually fit to the well-known crystal field theory or to the angular overlap model. The result of the f