Substrate and Positional Selectivity of Free Phenylium Ions toward Arenes in the Gas and Liquid Phases
β Scribed by Giancarlo Angelini; Yeghis Keheyan; Maurizio Speranza
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- German
- Weight
- 836 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0018-019X
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## Abstract Gasβphase mass spectrometric studies and calculations were performed for the reaction of naked phenylium ion with several benzene halides. From these reactions, the molecular ion for biphenyl as the predominant product was obtained only from the reaction of phenylium ions with iodobenze
The positive ion chemical ionization (CI (isobutane)), negative ion chemical ionization (NICI) electron attachment (CH,,, He) and NICI (OH-) spectra of the title compounds have been studied in detail with the aid of deuterium-labelled derivatives. me obtained results show that under CI conditions th