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The behaviour of stereoisomeric ions in the gas phase: 2—Negative and positive chemical ionization of cyclohexanehexacarboxylic methyl esters

✍ Scribed by Guido Audisio; Maria Grassi; Piero Traldi; Sergio Daolio

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
299 KB
Volume
20
Category
Article
ISSN
1076-5174

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✦ Synopsis

The positive ion chemical ionization (CI (isobutane)), negative ion chemical ionization (NICI) electron attachment (CH,,, He) and NICI (OH-) spectra of the title compounds have been studied in detail with the aid of deuterium-labelled derivatives. me obtained results show that under CI conditions the stereospecificity is retained. Interesting correlations with the condensed phase epimerization yields are emphasized.

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