Substitution versus elimination in gas-phase ionic reactions
โ Scribed by Wladkowski, Brian D.; Brauman, John I.
- Book ID
- 126117859
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 304 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Gas-phase pyrolyses of ethyl N-(5-cyanomethyl-1,3,4thiadiazol-3-yl)carbamate ( ), 1-benzoyl-3-(3-methylpyrazol-5-yl)thiourea ( ), 1-benzoyl-3-(5-methylisoxazol-3-yl)thiourea ( ), and 1-acetyl-3-(3-phenylpyrazol-5-yl)thiourea ( ) have been studied. These reactions were homogeneous and unimolecular. T
The competition between substitution (sN2), elimination (E2) and additiorrelimination (AE) reactions in the gas phase has been studied by using OH-and NH,as nucleophiles reacting with esters of acetylenedicarboxylic acid of general formula RO(O)CCZCC(O)OR'. By selectively varying R and R' it was pos