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Substitution Reactions with Photochemically Produced Acyl Radicals

✍ Scribed by Prof. Dr. Ulrich Schmidt

Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
117 KB
Volume
4
Category
Article
ISSN
0044-8249

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✦ Synopsis

Acyl chlorides are split into acyl and chlorine radicals by light of wavelength 254 my. Since the dissociation energy of the chlorine-hydrogen bond is considerably larger than that of the acyl-hydrogen bond, substitution of the substrate by acyl radicals is observed on irradiation of acid chlorides. On irradiation of acetyl chloride the following reactions take place:

BrZ CC14

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