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Substitution Reaction of 3-Ey Tritium Atoms with Methane 1

โœ Scribed by Chou, C. C.; Rowland, F. S.


Book ID
126998589
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
304 KB
Volume
88
Category
Article
ISSN
0002-7863

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A recent investigation of hydrogen abstraction by the trichloromethyl radical from l-substituted adamantanes has been reported by us (1). It was observed that appreciable halogen abstraction by the radical occurred for 1-fluoroadamantane and l-chloroadamantane. Similar halogen abstraction from adama

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The reactions with CHjF of photochemically produced tritium atoms from TBr have been studied at various v+xvelengths. The energy threshold is lower and the relative yield higher for F replacement than for H repkement in CHaF. These near-threshold substitution reactions are consistent with an inversi