## The pmence of a mdical rtabilizing group on the aql ring can lead to ring-expanded products. Although radical cyclisation methodology is presently the subject of much attention by the synthetic chemistry community,1 studies of cyclizations initiated by aryl radicals2 have not been extensive nor
β¦ LIBER β¦
Substituent Effects on Vinyl Radical Cyclizations onto Aryl Rings
β Scribed by Montevecchi, Pier Carlo; Navacchia, Maria Luisa
- Book ID
- 125898262
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 138 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Radical copolymerizations of ringβsubstituted __trans__βcinnamonitriles with olefins such as styrene and acrylonitrile were studied at 60Β°C. The copolymerization parameters of cinnamonitriles (M~1~) in the copolymerizations with styrene (M~2~) were determined to be __r__~1~ = 0,01 to 0,