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Substituent effects on the redox behavior of a series of chromium-phenanthroline complexes

โœ Scribed by Hughes, Michael C.; Macero, Daniel J.

Book ID
126149988
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
846 KB
Volume
13
Category
Article
ISSN
0020-1669

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๐Ÿ“œ SIMILAR VOLUMES

Substituent effects on the redox reactio
Substituent effects on the redox reactions of tetraphenylporphyrins
โœ Karl M Kadish; Mark M Morrison ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science โš– 543 KB

The effect of substituents on pi radical reactions of para-substituted tetraphenylporphyrins was investigated by cyclic voltammetry in methylene chloride. In all cases electron donating substituents produced a more difficult reduction and an easier oxidation. Plots of E1/2 vs. a yielded Hammett line