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Substituent effects on the hyperfine splitting constants of N,N-dimethylaniline cation radicals

✍ Scribed by Latta, B. M.; Taft, Robert W.


Book ID
127186106
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
861 KB
Volume
89
Category
Article
ISSN
0002-7863

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Vibronic effects on the hyperfine splitt
✍ Maurizio Guerra; Fernando Bernardi; Gian Franco Pedulli πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 371 KB

TheaN and a;H hyperfine splitting constants of pyridinyl are poorly reproduced by INDO molecular orbital calculations if assuming a planar geometry for the radical. A much better agreement with experiment has been found by evaluating: these constants from vibronic ~avef~n~tions even though at a ~mjq