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Substituent effects on the frontier molecular orbitais of aryl isonitriles

โœ Scribed by Randy F. Johnston; John C. Cooper

Book ID
113257175
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
834 KB
Volume
236
Category
Article
ISSN
0166-1280

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โœ Xiangyang Zhang; Werner M. Nau ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 79 KB ๐Ÿ‘ 2 views

Five aryl-substituted phenacetyl radicals (X = p-MeO, p-Me, H, p-Cl, p-CF 3 ) were generated by laser photolysis of the corresponding dibenzyl ketones in n-hexane and acetonitrile. The decarbonylation reaction was monitored through the rise in time-resolved absorption of the benzyl radical chromopho