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Substituent Effects on Stability and Isomerization Energies of Isocyanides and Nitriles

โœ Scribed by Sung, Kuangsen

Book ID
127357102
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
59 KB
Volume
64
Category
Article
ISSN
0022-3263

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## Abstract __Ab initio__ STOโ€3G geometryโ€optimized calculations have been performed on methyl, ethyl, and isopropyl cyanides and isocyanides, and the cations formed on abstraction of an ฮฑโ€hydride ion. Stabilization energies of the cations and cyanideโ€“isocyanide isomerization energies have been cal