Substituent Effects on Edge-to-Face Arom
β
Fiona J. Carver; Christopher A. Hunter; David J. Livingstone; James F. McCabe; E
π
Article
π
2002
π
John Wiley and Sons
π
English
β 944 KB
Chemical double mutant cycles have been used to measure the magnitude of edge-to-face aromatic interactions in hydrogen-bonded zipper complexes as a function of substituents on both aromatic rings. The interaction energies vary depending on the combination of substituents from +1.0 kJ mol-1 (repulsi