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Substituent effects on aromatic stacking interactions

✍ Scribed by Cockroft, Scott L.; Perkins, Julie; Zonta, Cristiano; Adams, Harry; Spey, Sharon E.; Low, Caroline M. R.; Vinter, Jeremy G.; Lawson, Kevin R.; Urch, Christopher J.; Hunter, Christopher A.


Book ID
118256696
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
619 KB
Volume
5
Category
Article
ISSN
1477-0520

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Substituent Effects on Edge-to-Face Arom
✍ Fiona J. Carver; Christopher A. Hunter; David J. Livingstone; James F. McCabe; E πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 944 KB

Chemical double mutant cycles have been used to measure the magnitude of edge-to-face aromatic interactions in hydrogen-bonded zipper complexes as a function of substituents on both aromatic rings. The interaction energies vary depending on the combination of substituents from +1.0 kJ mol-1 (repulsi