✦ LIBER ✦

Substituent Effects on 2-Norbornyl Solvolysis Rates. The 6,6-Dimethyl Group 1

✍ Scribed by von R. Schleyer, Paul; Donaldson, Malcolm M.; Watts, William E.

Book ID: 126405423
Publisher: American Chemical Society
Year: 1965
Tongue: English
Weight: 250 KB
Volume: 87
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01080a039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Polar effects in the solvolysis of 6-exo

Polar effects in the solvolysis of 6-exo-substituted endo-2-norbornyl p-toluenesulfonates

✍ W. Fischer; C.A. Grob; G. von Sprecher; A. Waldner 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 157 KB

Polar and anchimeric effects in the solv

Polar and anchimeric effects in the solvolysis of 6-endo-substituted 2-norbornyl-p-toluene-sulfonates

✍ Cyril A. Grob; Bettina Gunther; Reinhard Hanreich 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 192 KB

A study of the influence of 6-endo substituents on the reactivity of 2-exoand 2-endo-norbornyl p-toluenesulfonates 3 and 4, respectively, confirms that polar rather than steric effects control relative rates.

Solvent and Stereoelectronic Effects on

Solvent and Stereoelectronic Effects on the Solvolysis Rates of Oxaspirocyclopropanated 1-Norbornyl Triflates and Related Bridgehead Derivatives

✍ García Martínez, Antonio; de la Moya Cerero, Santiago; Teso Vilar, Enrique; Ga 📂 Article 📅 2008 🏛 American Chemical Society 🌐 English ⚖ 499 KB

Inductive, CC-hyperconjugative and frang

Inductive, CC-hyperconjugative and frangomeric effects in the solvolysis of 6-exo-substituted 2-exo-norbornyl p-toluenesulfonates

✍ W. Fischer; C.A. Grob; G. von Sprecher 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 172 KB

Polar versus steric effects in the solvo

Polar versus steric effects in the solvolysis of 6endo-substituted 2endo-norbornyl p-toluenesulfonates. Norbornanes, Part 8

✍ Cyril A. Grob; Bettina Günther; Reinhard Hanreich 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 337 KB 👁 1 views

## Abstract The solvolysis rates and products of the 6__endo__‐R‐substituted 2__endo__‐norbornyl toluenesulfonates **6a**–**6i** have been determined. The rates of **6a**–**6g** correlate with the inductive constants σ the 6__endo__‐substituents and are not related to the size of the latter. It is

Structural effects in solvolytic reactio

Structural effects in solvolytic reactions. 49. Steric effects as a major factor in the exo:endo rate ratios for the solvolysis of 2,7,7-trimethyl- and 2,6,6-trimethyl-2-norbornyl p-nitrobenzoates

✍ Brown, Herbert C.; Ikegami, Shiro; Vander Jagt, David L. 📂 Article 📅 1985 🏛 American Chemical Society 🌐 English ⚖ 817 KB