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Structural effects in solvolytic reactions. 49. Steric effects as a major factor in the exo:endo rate ratios for the solvolysis of 2,7,7-trimethyl- and 2,6,6-trimethyl-2-norbornyl p-nitrobenzoates

✍ Scribed by Brown, Herbert C.; Ikegami, Shiro; Vander Jagt, David L.

Book ID: 126968096
Publisher: American Chemical Society
Year: 1985
Tongue: English
Weight: 817 KB
Volume: 50
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00208a004

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📜 SIMILAR VOLUMES

Unusually low exo-endo rate ratio in the

Unusually low exo-endo rate ratio in the solvolysis of the 2,7,7-trimethyl-2-norbornyl p-nitrobenzoates. Evidence for steric effects as a major factor in the exo-endo rate and product ratios of norbornyl derivatives

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Structural effects in solvolytic reactions. 31. High exo:endo rate and product ratios in the solvolyses of the 2-methyl-, 2-phenyl-, and 2-(5'-coumaranyl)-exo-5,6-trimethylene-2-norbornyl p-nitrobenzoates

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Structural effects in solvolytic reactions. XI. Rates and products of solvolysis of 2-aryl- and 2-methyl-2-norbornenyl p-nitrobenzoates. Exo:endo rate ratio as a function of increasing electron demand

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Predominant exo substitution in the prod

Predominant exo substitution in the products from the solvolysis of 2-p-anisylcamphenilyl p-nitrobenzoates and related compounds. Further evidence for steric effects as a major factor in the exo:endo product ratios from tertiary norbornyl derivatives

✍ Takeuchi, Kenichi.; Brown, Herbert C. 📂 Article 📅 1968 🏛 American Chemical Society 🌐 English ⚖ 327 KB