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Substituent effects in unimolecular ion decompositions. XIII. The quantitative effect of product ion stability

✍ Scribed by McLafferty, F. W.; Bursey, Maurice M.

Book ID
127360056
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
263 KB
Volume
90
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Effect of substituents on the kinetic en
Effect of substituents on the kinetic energy release in unimolecular decompositions of substituted anisoles
✍ Helena FlorΓͺncio; Peter C. Vijfhuizen; Wigger Heerma; Geo Dijkstra πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 288 KB

## Abstract The kinetic energy relased on the loss of a CH~3~ β‹… radical from __para__ substituted anisoles appears to depend on the nature of the substituent. The application of the dual parameter equation of Yukawa and Tsuno yields a linear correlation with the __T__~0.5~‐values. The mesomeric eff