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Substituent Effects in the Reaction of OH Radicals with Aromatics: Toluene

✍ Scribed by Albarran, Guadalupe; Bentley, J.; Schuler, Robert. H.

Book ID: 118066734
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 570 KB
Volume: 107
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp030550u

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## Abstract Reactions of isopropyl and of undecyl radicals with __meta‐__ and __para__‐substituted toluenes are reported. The results demonstrate that the reactivities of toluenes are due to both benzyl‐H abstraction and addition of the alkyl radicals to the aromatic ring. Relative reactivities yie