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Substituent Effects in the Migration Step of the Baeyer−Villiger Rearrangement. A Theoretical Study

✍ Scribed by Reyes, Lino; Castro, Miguel; Cruz, Julián; Rubio, Manuel

Book ID
115537703
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
266 KB
Volume
109
Category
Article
ISSN
1089-5639

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An unusual effect of selenium substituen
An unusual effect of selenium substituents on the regiochemistry of a baeyer-villiger rearrangement
✍ Barry M. Trost; Peter Buhlmayer; Michael Mao 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 201 KB

The regioselectivity of a Baeyer-Villiger oxidation of a cyclobutanone is dependent upon the oxidation state of a proximal selenium substituent. for the selenium dioxide-hydrogen peroxide oxidation of ketones. Sharpless, K. B. ; Gordon, K.M. J. Am. Chem. Soq . 1976, 98, 300. 9. It can be argued that