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Stereoelectronic and steric effect in the Baeyer–Villiger rearrangement of steroidal α-chlorocyclobutanones

✍ Scribed by Zdzisław Paryzek; Hanna Koenig

Book ID
119375724
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
434 KB
Volume
68
Category
Article
ISSN
0040-4020

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Steroidal cyclobutanones, V. the baeyer-
Steroidal cyclobutanones, V. the baeyer-villiger rearrangement of α-substituted β-spirocyclobutanones
✍ Paryzek, Zdzislaw ;Blaszczyk, Krzysztof 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 477 KB

## Abstract The reaction of the steroidal spiro‐α,α‐dichlorocyclobutanone 1 carried out in basic H~2~O~2~/MeOH/THF solution proceeds with __cine__ substitution leading to the intermediate α‐chloro‐α‐methoxycyclobutanone 7 followed by the Baeyer‐Villiger rearrangement giving the spiro‐α‐chloro‐γ‐met