Substituent effects in the mass spectra of benzoyl hetarenes
✍ Scribed by Hans-Fr. Grützmacher; Ralf Schubert
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 362 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1076-5174
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📜 SIMILAR VOLUMES
The mass spectra of a series of mefa-and para-substituted phenyl acetates have been examined. Substituent effects have been correlated with A(AP-IP) values and by using the Harrison and Chin approach. The bond-cleavage and rearrangement reactions of phenyl acetates are compared with the correspondin
## Abstract Substited pivalanilides give rise to fragments corresponding to anilies on electron‐impact, which is due to the migration of a hydrogen atom from the __t__‐butyl group to the nitrogen. The Hammett correlation indicates that the formation of this fragment is favoured by electron‐donating