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Substituent effects in the mass spectra of acetanilides

✍ Scribed by J. R. Gilbert; A. J. Stace

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
165 KB
Volume
10
Category
Article
ISSN
1076-5174

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The mass spectra of a series of mefa-and para-substituted phenyl acetates have been examined. Substituent effects have been correlated with A(AP-IP) values and by using the Harrison and Chin approach. The bond-cleavage and rearrangement reactions of phenyl acetates are compared with the correspondin

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## Abstract Substited pivalanilides give rise to fragments corresponding to anilies on electron‐impact, which is due to the migration of a hydrogen atom from the __t__‐butyl group to the nitrogen. The Hammett correlation indicates that the formation of this fragment is favoured by electron‐donating