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Substituent effects in the acetylation of acylhydrazones of penta-O-acetyl-aldehydo-d-galactose

✍ Scribed by László Somogyi

Book ID
102641508
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
454 KB
Volume
165
Category
Article
ISSN
0008-6215

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## Abstract The reaction of alkenyl glycosides 2a–2c with MCPBA gives diasteroisomeric mixtures of epoxides 3 and 4. The asymmetric induction decreases in the order 2a ≫ 2b > 2c. The absolute configuration of epoxyalkyl glycosides is determined by correlation with (__R__)‐glycerinaldehyde in an ind