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Substituent effects in proton NMR of monosubstituted acetophenones: I

✍ Scribed by G. A. Caplin

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
436 KB
Volume
6
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Chemical shifts are reported for the acetyl protons in a series of para‐substituted acetophenones in a number of solvents, and substituent effects evaluated statistically by means of the Swain‐Lupton multiple correlation analysis. A basic set of substituents was built up by careful choice of substituted derivatives, and it was shown that this facilitated the possibility of valid comparisons of substituent effects between differing systems. Strong emphasis was placed on the idea of individuality of substituents and solvents.

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