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Substituent effects in the enantioselective reduction of acetophenones with nabh4 in the presence of β-cyclodextrin

✍ Scribed by Dr. André Deratani; Estelle Renard

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
690 KB
Volume
6
Category
Article
ISSN
0899-0042

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The opening of ortho-substituted phenyl oxiranes by borohydrides is described both in aqueous and solid phases. Some remarkable differences in the regioselectivity and inversion of enantioselectivity of oxirane ring-opening are reported. The results obtained are compared with previous studies and ha