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Substituent effects in free radical additions to alkenes

✍ Scribed by Martin Klessinger; Udo Höweler

Book ID
119116688
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
374 KB
Volume
138
Category
Article
ISSN
0166-1280

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Free radical addition of α-telluroesters
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✍ Nobuaki Kambe; Li-Biao Han; Shin-ichi Fujiwara; Noboru Sonoda 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB 👁 1 views

## Abstract α‐(Phenyltelluro)esters **2** reacted with electron‐rich alkenes **3** in the presence of a catalytic amount of azobisisobutyronitrile (AIBN) as an initiator to give the corresponding addition products **4**. This carbotelluration of alkenes proceeded via a radical chain mechanism invol