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Imidyl Radicals – Free-Radical Addition ofN1-Bromoimides to Alkenes

✍ Scribed by Lüring, Ulrich ;Kirsch, André

Publisher
Wiley (John Wiley & Sons)
Year
1993
Tongue
English
Weight
551 KB
Volume
126
Category
Article
ISSN
0009-2940

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📜 SIMILAR VOLUMES

Imidyl radicals. 3. Stereoselectivity of
Imidyl radicals. 3. Stereoselectivity of radical additions of N-haloimides to cyclic alkenes
✍ André Kirsch; Ulrich Lüning; Oliver Krüger 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 66 KB 👁 2 views

N-Haloimides (1 -5) are used in two types of radical chain reactions: (i) the selective Ziegler bromination of allylic and benzylic positions [1], which are bromine atom chain reactions [2] and (ii) imidyl radical [3, 4] chain reactions like substitutions and especially additions to double bonds [5,

Free radical addition of α-telluroesters
Free radical addition of α-telluroesters to alkenes
✍ Nobuaki Kambe; Li-Biao Han; Shin-ichi Fujiwara; Noboru Sonoda 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB 👁 1 views

## Abstract α‐(Phenyltelluro)esters **2** reacted with electron‐rich alkenes **3** in the presence of a catalytic amount of azobisisobutyronitrile (AIBN) as an initiator to give the corresponding addition products **4**. This carbotelluration of alkenes proceeded via a radical chain mechanism invol