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Substituent-Dependent Reactivity in the Photodimerization of N-Substituted Dibenz[b,f]azepines

✍ Scribed by Jens Querner; Thomas Wolff; Helmut Görner


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
260 KB
Volume
10
Category
Article
ISSN
0947-6539

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✍ Yusuf Yagci; Metin Hayri Acar; Anthony Ledwith 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 221 KB

N-chlorocarbonyl dibenz[b,f] azepine in conjunction with AgSbF6 initiated the cationic polymerization of c(-methylstyrene in methylene chloride. Polymer samples obtained this way contained terminal dibenzazepine units. Chain extension occurred upon irradiating these polymers with u.v. in benzene so