✦ LIBER ✦

Subnanosecond dynamics of the fluorescence and singlet absorption of s-tetrazine

✍ Scribed by Robin M. Hochstrasser; David S. King; Albert C. Nelson

Book ID: 103015313
Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 459 KB
Volume: 42
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80540-4

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✦ Synopsis

The fiuorescen~ hfetime, smgiet absorption de-y, and the S1 absorption spectrum of s-tetrazine have been mezsured in C6H6 solution at 300 K. Th? fluorescence was measured usin g a Duguay-Hansen hght gate and the trannent absorption was studied using a picosecond continuum generated from CC4 using a 1060 nm pulse. The spectrum was photographed with a single laser shot. The results are a new S1 spectrum peaking at 473 nm correspondmg to an allowed transtion; an S1 l&time from absorption of 424 f 75 ps; a spontaneous emission lifetime of 450 = 55 ps.

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