Doppler-free polarization spectroscopy in combination with double-resonance techniques and laser-induced fluorescence spectroscopy has been used to determine the X 'r+ground state with a dissociation energy De = 4950 cm-\* and to extract preliminary information about the perturbed excited D ' II sta
Sub-Doppler Spectroscopy of the LiH Molecule: The A–X System
✍ Scribed by N. Bouloufa; P. Cacciani; R. Vetter; A. Yiannopoulou
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 252 KB
- Volume
- 202
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The sub-Doppler analysis of the ( A 1 ⌺ ϩ -X 1 ⌺ ϩ ) system is performed for 6 LiH and 7 LiH by crossing an effusive beam of LiH by a cw tunable laser beam in the near UV; 384 lines are measured between 357 and 385 nm and assigned to 6 LiH and 7 LiH with an accuracy of 5 ϫ 10 Ϫ3 cm Ϫ1 . Accurate Dunham coefficients and their mass-dependent corrections are deduced for the A 1 ⌺ ϩ electronic state of both isotopomers from the combination of previously published data and these new ones.
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We report here new and more accurate molecular constants from sub-Doppler polarization spectroscopy of the A1Sigma+u-X1Sigma+g system of 6Li2 using single mode cw dye lasers. These new constants cover the range of vibrational levels from v" = 0-8 in the ground state and v' = 0-24 in the excited stat