Polymerizable styrenic surfactants (surfmers) and nonreactive analogs, have been applied in emulsion copolymerization of acrylic monomers in a seeded semibatch process. Stable core-shell latexes with low levels of coagulum and controlled particle size have been obtained; some of them, with either st
Styrenic Surfmers in Emulsion Polymerization of Acrylic Monomers. 3. Surface Analysis
✍ Scribed by Soula, Olivier; Pétiaud, Roger; Llauro, Marie-France; Guyot, Alain
- Book ID
- 126268686
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 86 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0024-9297
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Several polymerizable surfactants (surfmers) have been used in the semicontinuous emulsion copolymerization of styrene, butyl acrylate, and acrylic acid. Three of the (anionic) surfmers (sodium 11-crotonoyl undecan-1-yl sulfate, sodium 11-methacryloyl undecan-1-sulfate, and sodium sulfopropyl tetrad
The copolymerization of styrene with two polymerizable surfactants (surfmers) based on maleic acid (dodecyl sodium sulfopropyl maleate and tetradecyl sodium sulfopropyl maleate) was studied in batch emulsion polymerizations. The surfmer conversion was obtained by serum replacement with water and sub