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Study on the Reaction of Salicylic Acid with Dialkyl Phosphite by NMR and Electrospray Ionization Mass Spectrometry

✍ Scribed by Chen Xiao-Lan; Qu Ling-Bo; Guo Lei; Lu Jian-Sha; Liu Yan; Wu Jian-Li; Zhao Yu-Fen

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 118 KB
Volume: 23
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.200590733

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The reaction between salicylic acid and dialkyl phosphite was traced by electrospray ionization mass spectrometry and ^31^P NMR. All reactants, unstable intermediates and products were detected. The mechanism was proposed based on ESI‐MS results and ^31^P NMR profiles.

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