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Electrospray ionization mass spectrometry study on dipeptide 4-chlorobutyl ester produced from refluxing of amino acid with phosphoryl chloride in tetrahydrofuran

✍ Scribed by Gui Ji Zhou; Ze Liu; Tong Jian Wang; Peng Xiang Xu; Gou Tang; Yong Ye; Yu Fen Zhao


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
123 KB
Volume
40
Category
Article
ISSN
1076-5174

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✦ Synopsis


Abstract

Phosphoryl chloride was able to promote the formation of peptide and the ringopening of tetrahydrofuran (THF) followed by a sequence of successive reactions by simply refluxing. ESI multistage tandem mass spectrometry was applied to trace the reaction and elucidate the product structures, dipeptide 4‐chlorobutyl ester. Copyright © 2005 John Wiley & Sons, Ltd.