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Study on the influence of unsaturations on the formation of C-11, C-12, C-13 and C-14 membered rings

โœ Scribed by Denis Brillon; Pierre Deslongchamps

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
199 KB
Volume
27
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The intramolecular displacement of allylic and propargylic chlorides and primary bromides by malonate anion in eleven, twelve, thirteen and fourteen carbon chains containing either two, one or no unsaturation, is reported. At 2 x lo-* M, formation of cyclic monomers and dimers are observed in all cases.

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