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Study on Catalytic Effect of Copper(II) Complex on 1,10-Phenanthroline-H2O2-CTMAB Chemiluminescence Reaction and Its Analytical Applications

✍ Scribed by Z.P. Li; L.T. Dai; Z.J. Zhang


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
318 KB
Volume
52
Category
Article
ISSN
0026-265X

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✦ Synopsis


Through our flow injection analysis experiments, we discovered that an unsaturated complex of (\mathrm{Cu}) (II) and organic ligand had a strong catalytic effect on 1.10 -phenanthroline- (\mathrm{H}{2} \mathrm{O}{2}-\mathrm{CTMAB}) chemiluminescence reaction. Based on this mechanism, the new flow injection analysis methods for detection of some biological ligands were established. Detection limits are in the range of 2.7-90 pmol for amino acids. polyamines, and salicylic acids. 1995 Academic Press, Inc.


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