## Abstract A novel asymmetric monosubstituted 1,10‐phenanthroline, Hophen⋅0.5 H~2~O (1, Hophen=1__H__‐[1,10]phenanthrolin‐2‐one), was generated by a facile route, and a novel class of crystalline, d^10^‐metal, monomeric or oligomeric complexes of this ligand, namely [Hg(ophen)~2~]⋅4 H~2~O⋅CH~2~Cl~
Synthetic and Structural Studies on Copper 1 H-[1,10]-Phenanthrolin-2-one Coordination Complexes: Isolation of a Novel Intermediate During 1,10-Phenanthroline Hydroxylation
✍ Scribed by Katherine B. Szpakolski; Kay Latham; Colin J. Rix; Jonathan M. White; Boujemaa Moubaraki; Keith S. Murray
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 276 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0947-6539
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## Abstract The hydrothermal reaction of 1__H__‐1,10‐phenanthroline‐2‐one (Hophen), zinc acetate, benzoic acid (Hba), and triethylamine (3.0 mL) yields the tetranuclear complex [Zn~4~(μ~3~‐OH)~2~(ophen)~4~(ba)~2~] (2), which features a chair‐like Zn~4~(μ~3~‐OH)~2~ cluster with two ba ligands centro
## Abstract A novel ligand 3‐(1__H__‐imidazo[4,5‐__f__][1,10]phenanthrolin‐2‐yl)‐4__H__‐1‐benzopyran‐4‐one (ipbp) and its ruthenium(II) complexes [Ru(bpy)~2~(ipbp)]^2+^ (**1**) and [Ru(ipbp)(phen)~2~]^2+^ (**2**) (bpy=2,2′‐bipyridine, phen=1,10‐phenanthroline) were synthesized and characterized by
Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,
Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê