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Study of the Reformatsky Reaction; Efficient Procedure for the Preparation of Bromoacetic Ester in Large Quantities

โœ Scribed by Natelson, Samuel.; Gottfried, Sidney P.


Book ID
121505564
Publisher
American Chemical Society
Year
1939
Tongue
English
Weight
228 KB
Volume
61
Category
Article
ISSN
0002-7863

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The reaction of lithium ester enolates w
โœ Michael W. Rathke; Jeffrey Deitch ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 158 KB

Lithium ester enolates, prepared by the reaction of lithium N-isopropylcyclohexylamide (LIICA) with esters at -78' (eq. 1); react with acid chlorides at this same low temperature to provide satisfactory yields of the corresponding S-keto esters (eq. II). This procedure represents an exceedingly vers