The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ? 0.3) x 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experi
Study of the reactions of palladium(II) macrocyclic tetraamine complexes with hydroxyl and methyl radicals
โ Scribed by Jochen Lilie; William L. Waltz; Savitri Chandrasekhar
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 721 KB
- Volume
- 246
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Absolute rate coefficients for the reactions of the hydroxyl radical with ethane (kl, 297-800 K) and propane (kz, 297-690 K) were measured using the flash photolysis-resonance fluorescence technique. The rate coefficient data were fit by the following temperature-dependent expressions, in units of c
The kinetics of the reaction CH3 + 0 2 (+M) -+ CH302 (+MI have been studied, using the technique of flash photolysis and kinetic spectroscopy to follow the methyl radical concentration. The order of the reaction lies between 2 and 3 throughout the range of pressure from 25 to 380 torr at 22"C, and t