The effects of oxidation of activated carbons are studied by means of high-pressure methane adsorption. Decreases in amounts adsorbed and adsorption enthalpies after oxidation are observed. Thermodynamic analysis of adsorption isotherms using the virial-type thermal equation of adsorption is present
Study of the porous structure of active carbons by nitrogen adsorption and n-nonane preadsorption
✍ Scribed by J. de D. Casquero-Ruiz; J.M. Guil; J. de D. López-González; A. Ruiz-Paniego
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 584 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0008-6223
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✦ Synopsis
Nitrogen isotherms have been determined at 77 K on four active carbons, used as adsorbents in gas masks, before and after n-nonane ~readsorption. The four carbons contain both micro and mesopores. After n-nonane preadsorption, mesoporosity is still observed, together with a, low pressure hysteresis that can be ascribed to the penetration of Nz into the porous system through n-nonane stoppers that block some of the pore entrances. Results have been analyzed by means of the Dubinin-Radushkevich (DR) equation and the OL, method.
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