Study of the formation of the nonclassical C5H5C+cation in the gas phase by the ionic cyclotron resonance spectroscopy method
✍ Scribed by R. I. Pikver; é. R. Suurmaa; é. T. Lippmaa; Yu. S. Nekrasov; D. V. Zagorevskii; V. F. Sizoi
- Book ID
- 112445442
- Publisher
- Springer
- Year
- 1983
- Tongue
- English
- Weight
- 221 KB
- Volume
- 32
- Category
- Article
- ISSN
- 1573-9171
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📜 SIMILAR VOLUMES
The kinetics of the gas-phase dehydrogenation of cyclopentane to cyclopentene is found to be consistent with a slow attack by a n I atom (step 4, text) on cyclopentane in the range 282-382OC. The measured rate constants fit the Xrrhenius equation, log k, = 11.95 f 0.08 -(24.9 f 0.23)/0 1 mole-l sec-
The gas-phase dehydrogenation of cyclopentene to cyclopentadiene catalyzed by iodine in. the range 178-283'C has been found to obey a rate law consistent with the slow rate-determining step, I + c-C5Hs --t HI + c-C5H, , log [ka/(l moleL1 sec-')I = 10.25 \* 0.08 -(12.26 f 0.18)/0, where 0 = 2.303RT i