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Study of the effect of certain titanium compounds on the thermo-oxidative stability of 1,4-cis-polyisoprene

✍ Scribed by L.G. Angert; A.I. Andreyeva; A.S. Kuz'minskii

Book ID
118358421
Publisher
Elsevier Science
Year
1968
Weight
346 KB
Volume
10
Category
Article
ISSN
0032-3950

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A detailed account of the mechanism of crosslinking in the cis-1,4-polyisoprene (1R)tetramethylthiuram disulfide (TMTD ) -ZnO system is given. Many experimental observations were harmonized in terms of a radical mechanism, rather than an ionic mechanism. Electron spin resonance (ESR) spectra on the