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Participation of antioxidants in the initiation of cis-1,4 polyisoprene oxidation

✍ Scribed by Rosík, Ladislav

Book ID
104534146
Publisher
Wiley (John Wiley & Sons)
Year
1967
Tongue
English
Weight
151 KB
Volume
5
Category
Article
ISSN
0449-2986

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✍ F. W. H. Kruger; W. J. McGill 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 727 KB

A detailed account of the mechanism of crosslinking in the cis-1,4-polyisoprene (1R)tetramethylthiuram disulfide (TMTD ) -ZnO system is given. Many experimental observations were harmonized in terms of a radical mechanism, rather than an ionic mechanism. Electron spin resonance (ESR) spectra on the