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Kinetics of the thermooxidative degradation of cis-1,4-polyisoprene in bulk in the presence of phenol antioxidants

โœ Scribed by V.V. Pchelintsev; Ye.T. Denisov


Book ID
118967625
Publisher
Elsevier Science
Year
1983
Weight
495 KB
Volume
25
Category
Article
ISSN
0032-3950

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A detailed account of the mechanism of crosslinking in the cis-1,4-polyisoprene (1R)tetramethylthiuram disulfide (TMTD ) -ZnO system is given. Many experimental observations were harmonized in terms of a radical mechanism, rather than an ionic mechanism. Electron spin resonance (ESR) spectra on the