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Study of the conformations of some α-hydroxy and α-methoxy ketones

✍ Scribed by E. Kh. Kazakova; G. R. Davletshina; A. N. Vereshchagin


Book ID
112449214
Publisher
Springer
Year
1987
Tongue
English
Weight
291 KB
Volume
36
Category
Article
ISSN
1573-9171

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A kinetic study of the oxidation of α-hy
✍ R. Natarajan; N. Venkatasubramanian 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 346 KB

## Abstract The oxidation of α‐hydroxy acids and α‐hydroxy ketones by Br(V) follows the rate‐law However, the former reaction exhibits a second‐order dependence on hydrogen ion concentration while the latter reaction has a third‐order dependence. A mechanism involving a slow formation of a bromate