Study of relations governing the distribution of composition of reaction products of propylene oxide with alcohols
β Scribed by Ya. Khlebitskii; M.G. Makarov; V.F. Shvets
- Book ID
- 118360989
- Publisher
- Elsevier Science
- Year
- 1975
- Weight
- 314 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0032-3950
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Reaction of cyclomalto-hexaose, -heptaose, or -octaose with propylene oxide in strong aqueous alkali gave products in which distribution of the degrees of substitution was relatively narrow and nearly symmetrical, and increased with the average degree of substitution. When an equimolar mixture of cy
## Abstract Rate constants for direct reactions of propylene oxide with certain aminoisopropanols in the presence of basic catalysts were studied at a temperature of 363β383 K. This reaction was found to be of the first order in propylene oxide, amino alcohol and catalyst. The observed kinetics are