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Study of peroxy radicals in polytetrafluoroethylene according to 2-mm ESR spectra

✍ Scribed by O. Ya. Grinberg; A. A. Dubinskii; O. G. Poluëktov; Ya. S. Lebedev


Book ID
112358385
Publisher
Springer
Year
1982
Tongue
English
Weight
682 KB
Volume
17
Category
Article
ISSN
0040-5760

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All arrangements and procedures for steady-state and time-resolved ESR were as described in [4]. The radicals Me,C and Me3C02CCH, were generated by photolysis of the corresponding disubstituted ketones. These undergo type-I cleavage from a short-lived triplet state followed by a fast decarbonylation