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Conformational transitions and barriers to rotation in the ESR spectra of 2,6-di-tert-butyl-4-aminophenoxyl radicals

✍ Scribed by G. A. Abakumov; E. S. Klimov


Publisher
SP MAIK Nauka/Interperiodica
Year
1974
Tongue
English
Weight
270 KB
Volume
15
Category
Article
ISSN
0022-4766

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Radical pairs are formed by photolysis of single crystals of 2,6-di-tert-butyl-4-methylphenol (ionol) (1) or 2,6-di-tert-butylphenol (2 ), doped by several different molecules, and investigated by the EPR method. A possible two-hydrogen-atom transfer is discussed as the photochemical act.