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Isotropic and solid-state esr spectra of the radical ion pairs of 2,4,6-Tri-tert-butyl thiobenzaldehyde

✍ Scribed by Angelo Alberti; Gian Franco Pedulli; Giuseppe Placucci


Publisher
Elsevier Science
Year
1991
Weight
479 KB
Volume
93
Category
Article
ISSN
0022-2364

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Radical pairs are formed by photolysis of single crystals of 2,6-di-tert-butyl-4-methylphenol (ionol) (1) or 2,6-di-tert-butylphenol (2 ), doped by several different molecules, and investigated by the EPR method. A possible two-hydrogen-atom transfer is discussed as the photochemical act.